GEOCHEMISTRY OF LATE CENOZOIC BASALTS
IN VIỆT
PHẠM TÍCH XUÂN1,
NGUYỄN HOÀNG1,2, LEE HYUN KOO3
1Institute of
Geosciences, AS&T VN, Hoàng Quốc Việt, Hà Nội
2Institute of Geosciences, Geological Survey of Japan, Tsukuba,
Japan
3Chungnam National University, Republic of Korea
Abstract: The
Late Cenozoic basalts consist of two main series related to two eruptive
episodes. The early episode (bN1-N21)
comprises voluminous tholeiitic and olivine basalts, erupted from extensional
fissures. The late episode (bN22-Q), formed by
central eruptions, comprises mainly alkaline basalts. The lower series basalts
are characterized by high SiO2, low TiO2, FeO*, Na2O+K2O
and P2O5, while the upper series basalts have low SiO2,
high TiO2, FeO*, Na2O+K2O and P2O5
and usually have higher contents of incompatible elements. Diversity of
compositions of basalts was due to the difference of melt generation conditions
(P-T, fluid), degree of partial melting or heterogeneity of sources. The lower
series were generated under intensive extension of territory (high degree of
partial melting), in shallow mantle (low pressure). In contrast, the upper
series were generated under limited extension of territory (low degree of
partial melting), in deeper mantle (high pressure). The differentiation in
intensity and appearance of W-E extension is the cause of feature of
distribution of late Cenozoic basalts: most of the eruptive centres are
concentrated in the southern part of
INTRODUCTION
Cenozoic basaltic
eruption in Việt
Late Cenozoic volcanic activities in Việt
Figure 1. Distributive schema of Late
Cenozoic basalts in Việt
Some features of the
basaltic covers are presented in the Table 1. According to recent studies [5,
10], Late Cenozoic volcanic activities have been subdivided into two main
phases: early phase of Miocene - Early Pliocene age (bN1-N21)
and, late phase of Late Pliocene - Quaternary (bN22-Q).
Corresponding to these two effusive phase there are two basalt groups. Basalts
of the early phase are characterized by the type of effusion along fractures
forming large basaltic plateaux, basaltic flows and occupying the major part of
Cenozoic effusives. They are composed mainly of quartz tholeiite and olivine
tholeiite. Basalts of the late phase are characterized by the type of central
effusion leaving many volcanic structures, such as cones, maars … and usually
have the eruptive character with such products as volcanic bombs, ashes, tuffs
and pyroclastics. They are characterized by the predominance of high-alkaline
basalts. Especially, in high-alkaline basalts of the late phase there usually
are mantle xenoliths, such as spinel lherzolite, harzburgite, wehrlite,
pyroxenite, etc. and large crystals of augite, olivine and plagioclase.
Table 1. Features of
Late Cenozoic basaltic covers
Localities |
Areas (km2) |
Thickness
(m) |
Age
(Ma) |
Localities |
Areas (km2)) |
Thickness |
Age
|
Lũng Pô Hồ |
1 |
100 |
? |
Buôn Ma
Thuột |
3,800 |
260 |
8,9 - 1,63 |
Điện Biên
Phủ |
2 |
- |
5,8 |
Pleiku |
>4,000 |
> 440 |
7,4 - 1,59 |
Nghĩa Đàn |
6 |
- |
5,9 |
5 |
- |
16,8 -
1,68 |
|
Quảng Trị |
> 12 |
- |
7,8 - 0,4 |
Xuân Lộc |
2,400 |
> 130 |
11,58 -
0,44 |
Đà Lạt |
2,500 |
300 |
17,6-0,37 |
|
|
|
2,5 -
(1923) |
Phước Long |
> 6,000 |
250 |
9,1 - 4,6 |
|
|
|
|
II. METHOD OF
ANALYSIS
Samples used in analysis
consist of fresh rock samples selected from drill cores and surface exposures
taken from almost all basalt groups described in [4, 8-10]. The components of
main elements have been analyzed by XRF method on the Japanese measurer
III. RESULTS OF
1. Major element
components
The MgO content largely oscillates from –4.98% (Phước
Long basalts) to 12.96% (Xuân Lộc basalts). On the CIPW classification diagram
(Fig. 2) the major part of basalts fall into the field of quartz tholeiite (QT)
with components bearing converted quartz, and olivine tholeiite (OT) with
components bearing converted olivine and hypersthene; lesser there is alkaline
basalt (AB) bearing under 5% converted nepheline and, rarer, there is basanite
bearing over 5% converted nepheline.
The correlation between rock forming oxides is presented
in the diagram of Figure 3. SiO2 and MgO have rather clear negative
correlation, reflecting two groups of main elements: high- and low-SiO2
corresponding to basalts of the early and late phases (Fig. 3a). The TiO2
content of Late Cenozoic
Figure 2. Composition of Cenozoic basalts in
Việt
(based on the Table 2 with the combination with data of Nguyễn Hoàng et al [4,
5])
Note: Basalts of the early phase: 1) Đà Lạt, 3)
Pleiku, 5) Buôn Ma Thuột, 7) Xuân Lộc, 9) Phước Long, 13) Điện Biên, 14) Kông
Plông, 15) Lũng Pô Hồ; Basalts of the late phase: 2) Đà Lạt, 4)
Pleiku, 6) Buôn Ma Thuột, 8) Xuân Lộc; Undifferentiated
basalts: 10) Phú Quý, 11) Quảng Ngãi, 12) Quảng Trị; QT – quartz tholeiite, OT –
olivine tholeiite, AB – alkaline basalt.
Figure 3. Diagram of correlation between rock
forming oxides and MgO
in Cenozoic basalts in Việt Nam (Symbols
seen in Fig. 2)
Table 2. Composition
of major and trace elements in Cenozoic basalts in Việt Nam
Samples |
DL-I |
DL-I |
DL-I |
DL-II |
DL-II |
Plog |
Plog |
XL-I |
XL-II |
XL-II |
XL-II |
BMTI |
BMTII |
PL-I |
PL-I |
|
1 |
2 |
3 |
4 |
5 |
6 |
7 |
8 |
9 |
10 |
11 |
12 |
13 |
14 |
15 |
SiO2 |
54.16 |
52.99 |
49.75 |
53.37 |
54.4 |
52.44 |
51.37 |
53.13 |
45.13 |
48.83 |
52.19 |
46.71 |
49.43 |
54.36 |
47.47 |
TiO2 |
1.61 |
1.87 |
2.3 |
1.75 |
1.54 |
1.54 |
1.82 |
1.86 |
2.32 |
2.64 |
1.66 |
1.97 |
2.15 |
1.5 |
2.93 |
Al2O3 |
15.08 |
13.93 |
14.13 |
16.69 |
14.69 |
14.35 |
14.8 |
14.39 |
12.37 |
14.27 |
14.67 |
13.81 |
15.26 |
14.91 |
13.66 |
FeO* |
9.1 |
10.88 |
11.36 |
10.16 |
9.38 |
11.2 |
10.9 |
10.25 |
11.6 |
11.38 |
10.90 |
11.19 |
11.53 |
8.67 |
11.41 |
MnO |
0.14 |
0.19 |
0.14 |
0.12 |
0.14 |
0.14 |
0.15 |
0.15 |
0.18 |
0.16 |
0.13 |
0.17 |
0.16 |
0.09 |
0.16 |
MgO |
7.51 |
7.9 |
7.96 |
4.47 |
6.93 |
7.88 |
6.54 |
8.02 |
12.85 |
9.41 |
7.85 |
11.63 |
7.57 |
7.63 |
9.44 |
CaO |
6.77 |
7.04 |
7.11 |
4.85 |
6.99 |
7.03 |
7.09 |
8.36 |
7.62 |
5.85 |
8.27 |
7.38 |
5.87 |
6.6 |
7.62 |
Na2O |
2.36 |
2.23 |
1.68 |
4.26 |
2.22 |
1.99 |
2.31 |
3.01 |
3.18 |
2.45 |
3.12 |
2.67 |
3.73 |
1.94 |
2.17 |
K2O |
1.59 |
1.3 |
1.82 |
3.23 |
1.09 |
1.03 |
1.01 |
1.16 |
2.87 |
3.27 |
1.10 |
2.34 |
3.76 |
1.23 |
1.7 |
P2O5 |
0.31 |
0.3 |
0.48 |
0.75 |
0.19 |
0.28 |
0.26 |
0.34 |
1.08 |
0.97 |
0.32 |
0.6 |
1.03 |
0.23 |
0.75 |
Tổng |
98.63 |
98.64 |
96.73 |
99.65 |
97.58 |
97.88 |
96.25 |
100.67 |
99.19 |
99.24 |
100.21 |
98.47 |
100.5 |
97.15 |
97.29 |
Mg# |
59.77 |
56.65 |
55.78 |
44.19 |
57.08 |
55.88 |
51.92 |
58.48 |
66.60 |
59.81 |
56.45 |
65.17 |
54.17 |
61.30 |
59.83 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Cr |
380 |
444 |
338 |
470 |
326 |
373 |
442 |
253 |
805 |
606 |
364 |
578 |
517 |
405 |
475 |
Ni |
275 |
348 |
353 |
310 |
256 |
364 |
350 |
318 |
647 |
498 |
475 |
527 |
416 |
330 |
395 |
V |
136 |
160 |
169 |
81 |
127 |
153 |
164 |
187 |
177 |
135 |
145 |
185 |
124 |
115 |
202 |
Cu |
90 |
89 |
84 |
78 |
109 |
88 |
100 |
82 |
132 |
122 |
108 |
93 |
77 |
96 |
103 |
Zn |
176 |
189 |
239 |
237 |
153 |
167 |
221 |
351 |
251 |
278 |
271 |
21 |
227 |
175 |
321 |
Rb |
37 |
25 |
31 |
79 |
18 |
14 |
15 |
100 |
75 |
71 |
85 |
81 |
67 |
15 |
53 |
Sr |
309 |
337 |
408 |
701 |
222 |
301 |
354 |
1371 |
831 |
842 |
837 |
637 |
949 |
418 |
665 |
Ba |
428 |
335 |
416 |
761 |
193 |
383 |
236 |
635 |
703 |
691 |
697 |
572 |
587 |
263 |
684 |
Pb |
10.5 |
10.7 |
11.0 |
9.9 |
13.0 |
11.8 |
15.0 |
12.0 |
14.2 |
9.8 |
15.8 |
10.1 |
16.7 |
13.0 |
12.0 |
U |
1.1 |
1.2 |
0.9 |
2.0 |
0.5 |
1.1 |
0.6 |
2.0 |
2.8 |
2.0 |
2.2 |
1.5 |
2.2 |
0.6 |
2.0 |
Zr |
110 |
120 |
161 |
275 |
83 |
92 |
126 |
375 |
278 |
296 |
318 |
146 |
251 |
100 |
271 |
Nb |
23 |
27 |
39 |
68 |
14 |
22 |
16 |
105 |
79 |
79 |
82 |
59 |
78 |
15 |
67 |
Ta |
1.4 |
1.7 |
2.4 |
5.0 |
0.9 |
1.3 |
1.1 |
6.6 |
5.2 |
5.0 |
5.4 |
3.5 |
4.4 |
0.9 |
6.5 |
La |
19.4 |
21.4 |
2.8 |
53.5 |
11.6 |
15.8 |
15.0 |
76.0 |
78.4 |
74.0 |
74.5 |
41.5 |
67.9 |
15.3 |
53.2 |
Ce |
37.0 |
38.3 |
55.6 |
98.3 |
22.1 |
30.2 |
31.4 |
146.4 |
145.2 |
141.0 |
141.0 |
74.5 |
125.8 |
30.5 |
105.9 |
Pr |
4.6 |
4.5 |
6.9 |
11.6 |
2.7 |
3.8 |
4.2 |
17.6 |
16.7 |
17.0 |
16.5 |
8.7 |
14.6 |
3.9 |
13.0 |
Nd |
14.3 |
12.9 |
18.9 |
31.1 |
7.9 |
10.9 |
13.0 |
48.9 |
42.8 |
44.0 |
44.1 |
23.8 |
37.4 |
11.4 |
34.5 |
Sm |
3.6 |
3.8 |
5.0 |
7.8 |
2.7 |
3.3 |
3.8 |
10.8 |
8.8 |
10.0 |
9.7 |
5.7 |
8.2 |
3.4 |
8.3 |
Eu |
1.4 |
1.5 |
1.8 |
2.9 |
1.1 |
1.4 |
1.5 |
3.7 |
2.9 |
3.0 |
3.3 |
2.1 |
2.8 |
1.3 |
2.8 |
Gd |
4.8 |
5.3 |
6.2 |
9.3 |
3.9 |
4.3 |
5.2 |
13.0 |
10.8 |
12.0 |
11.7 |
6.8 |
9.5 |
4.3 |
9.5 |
Tb |
0.9 |
1.1 |
1.1 |
1.6 |
0.8 |
0.9 |
1.1 |
2.1 |
1.7 |
2.0 |
1.9 |
1.2 |
1.5 |
0.8 |
1.7 |
Dy |
3.5 |
4.2 |
4.1 |
5.0 |
3.2 |
3.3 |
4.1 |
6.8 |
5.5 |
6.0 |
6.3 |
4.2 |
5.0 |
3.0 |
5.5 |
Ho |
0.9 |
1.1 |
1.0 |
1.0 |
0.9 |
0.9 |
1.1 |
1.6 |
1.3 |
2.0 |
1.5 |
1.1 |
1.1 |
0.8 |
1.3 |
Er |
1.8 |
2.1 |
1.9 |
1.8 |
1.7 |
1.7 |
2.1 |
2.9 |
2.6 |
3.0 |
3.0 |
2.0 |
2.1 |
1.4 |
2.4 |
Yb |
1.4 |
1.7 |
1.5 |
1.1 |
1.4 |
1.3 |
1.7 |
1.9 |
1.8 |
2.0 |
2.1 |
1.5 |
1.4 |
1.1 |
1.7 |
Lu |
0.3 |
0.3 |
0.3 |
0.2 |
0.3 |
0.3 |
0.4 |
0.4 |
0.4 |
0.1 |
0.4 |
0.3 |
0.3 |
0.2 |
0.3 |
Y |
21.5 |
26.5 |
2.4 |
25.0 |
21.2 |
20.8 |
26.4 |
36.0 |
31.1 |
36.0 |
36.8 |
25.7 |
27.1 |
18.3 |
31.2 |
Th |
5.3 |
6.4 |
6.1 |
12.2 |
3.2 |
4.2 |
3.1 |
15.2 |
15.0 |
13.0 |
12.8 |
9.2 |
12.5 |
3.8 |
10.1 |
Hf |
3.7 |
4.1 |
5.0 |
8.1 |
3.0 |
3.2 |
4.2 |
10.8 |
7.6 |
9.0 |
8.6 |
4.8 |
7.0 |
3.3 |
7.6 |
Table 2 (continued)
Samples |
PL-I |
PL-II |
PL-II |
PL-II |
PL-II |
PL-II |
PQ |
Re |
Qtri |
Qtri |
KPLg |
KPLg |
LPH |
LPH |
LPH |
|
16 |
17 |
18 |
19 |
20 |
21 |
22 |
23 |
24 |
25 |
26 |
27 |
28 |
29 |
30 |
SiO2 |
52.66 |
50.94 |
49.89 |
51.06 |
50.58 |
50.60 |
50.73 |
52.33 |
52.56 |
49.59 |
52.97 |
51.57 |
50.81 |
51.84 |
51.68 |
TiO2 |
1.98 |
1.98 |
2.64 |
2.08 |
2.21 |
2.21 |
2.55 |
2.11 |
2.13 |
2.47 |
1.77 |
1.89 |
2.19 |
2.34 |
2.24 |
Al2O3 |
13.33 |
14.69 |
14.96 |
15.9 |
13.96 |
13.96 |
13.73 |
15.83 |
15.54 |
14.82 |
15.04 |
14.24 |
13.04 |
13.34 |
12.88 |
FeO* |
10.81 |
10.15 |
11.16 |
10.68 |
11.60 |
11.60 |
10.86 |
10.09 |
9.45 |
10.55 |
9.77 |
10.00 |
9.78 |
9.73 |
9.49 |
MnO |
0.14 |
0.16 |
0.15 |
0.22 |
0.13 |
0.13 |
0.14 |
0.13 |
0.2 |
0.15 |
0.14 |
0.13 |
0.16 |
0.14 |
0.14 |
MgO |
8.07 |
7.91 |
8.07 |
4.94 |
6.94 |
6.94 |
8.12 |
7.59 |
5.7 |
8.83 |
8.05 |
7.45 |
9.21 |
8.97 |
9.49 |
CaO |
8.45 |
6.04 |
6.73 |
5.12 |
8.50 |
8.50 |
7.13 |
7.05 |
6.33 |
7.4 |
7.01 |
8.82 |
7.45 |
6.24 |
6.99 |
Na2O |
2.95 |
3.15 |
2.24 |
3.66 |
3.42 |
3.42 |
2.35 |
2.13 |
2.69 |
2.39 |
2.14 |
2.94 |
2 |
1.91 |
1.89 |
K2O |
1.41 |
2.56 |
2.46 |
3.73 |
2.08 |
2.08 |
2.21 |
2.15 |
2.1 |
1.99 |
1.84 |
1.70 |
2.91 |
3.15 |
3.07 |
P2O5 |
0.31 |
0.6 |
0.69 |
0.76 |
0.52 |
0.82 |
0.61 |
0.59 |
0.51 |
0.55 |
0.38 |
0.37 |
0.63 |
0.59 |
0.56 |
Total |
100.11 |
98.18 |
98.98 |
98.17 |
99.94 |
100.26 |
98.43 |
100 |
97.21 |
98.73 |
99.11 |
99.11 |
98.16 |
98.25 |
98.44 |
Mg# |
57.33 |
58.38 |
56.55 |
45.43 |
51.85 |
51.85 |
57.37 |
57.52 |
52.05 |
60.10 |
59.73 |
57.28 |
62.90 |
62.40 |
64.29 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Cr |
484 |
742 |
364 |
422 |
593 |
272 |
480 |
554 |
383 |
373 |
471 |
282 |
630 |
462 |
631 |
Ni |
400 |
513 |
370 |
325 |
485 |
379 |
434 |
377 |
316 |
276 |
375 |
318 |
416 |
379 |
466 |
V |
184 |
129 |
178 |
99 |
149 |
181 |
160 |
143 |
166 |
159 |
135 |
153 |
175 |
173 |
183 |
Cu |
91 |
90 |
112 |
89 |
85 |
89 |
82 |
105 |
72 |
89 |
111 |
75 |
127 |
113 |
106 |
Zn |
302 |
242 |
242 |
261 |
331 |
286 |
257 |
223 |
216 |
245 |
209 |
218 |
248 |
241 |
247 |
Rb |
48 |
173 |
165 |
107 |
94 |
54 |
18 |
51 |
49 |
37 |
46 |
44 |
263 |
92 |
85 |
Sr |
675 |
738 |
603 |
1124 |
1034 |
570 |
666 |
508 |
501 |
663 |
449 |
392 |
509 |
493 |
515 |
Ba |
512 |
851 |
723 |
820 |
860 |
750 |
538 |
457 |
529 |
509 |
562 |
484 |
868 |
589 |
777 |
Pb |
11.1 |
19.0 |
13.2 |
14.2 |
13.0 |
9.8 |
10.2 |
13.9 |
16.7 |
10.4 |
15.5 |
13.8 |
21.0 |
10.9 |
18.0 |
U |
2.0 |
2.5 |
1.4 |
4.0 |
3.3 |
1.6 |
1.5 |
2.3 |
0.8 |
1.3 |
1.5 |
1.0 |
1.4 |
1.0 |
0.9 |
Zr |
258 |
297 |
214 |
436 |
362 |
205 |
191 |
206 |
157 |
135 |
135 |
142 |
189 |
188 |
187 |
Nb |
61 |
81 |
60 |
119 |
116 |
58 |
44 |
49 |
40 |
38 |
26 |
28 |
53 |
55 |
54 |
Ta |
4.1 |
5.7 |
3.9 |
8.0 |
7.0 |
3.6 |
2.9 |
1.8 |
2.4 |
2.7 |
1.7 |
2.0 |
3.7 |
3.6 |
3.2 |
La |
50.9 |
87.0 |
44.2 |
95.8 |
95.1 |
44.3 |
41.3 |
45.3 |
33.3 |
29.9 |
25.1 |
26.1 |
41.7 |
37.8 |
36.0 |
Ce |
99.9 |
130.4 |
85.3 |
170.7 |
175.5 |
85.1 |
76.5 |
85.8 |
62.7 |
56.2 |
49.2 |
51.1 |
79.7 |
70.8 |
70.1 |
Pr |
12.4 |
15.5 |
10.2 |
18.8 |
20.3 |
10.2 |
9.7 |
10.2 |
7.5 |
6.8 |
6.1 |
6.3 |
9.9 |
9.3 |
9.1 |
Nd |
34.2 |
38.7 |
28.1 |
46.1 |
51.8 |
27.5 |
27.0 |
26.9 |
21.1 |
20.2 |
18.2 |
17.7 |
29.5 |
26.8 |
26.2 |
Sm |
7.9 |
8.2 |
6.7 |
9.6 |
11.1 |
6.5 |
6.8 |
6.2 |
5.5 |
4.7 |
4.5 |
4.5 |
7.0 |
6.9 |
6.8 |
Eu |
2.7 |
3.0 |
2.5 |
3.4 |
3.8 |
2.4 |
2.4 |
2.1 |
1.9 |
1.8 |
1.6 |
1.7 |
2.3 |
2.3 |
2.3 |
Gd |
9.4 |
10.1 |
8.0 |
11.4 |
13.4 |
8.0 |
8.3 |
7.7 |
6.6 |
5.6 |
5.7 |
5.7 |
7.9 |
7.8 |
7.8 |
Tb |
1.6 |
1.7 |
1.4 |
1.8 |
2.1 |
1.4 |
1.4 |
1.3 |
1.2 |
1.0 |
1.1 |
1.1 |
1.3 |
1.4 |
1.4 |
Dy |
5.4 |
5.8 |
4.7 |
5.8 |
6.4 |
4.7 |
5.1 |
4.4 |
4.1 |
3.3 |
3.9 |
4.0 |
4.6 |
4.7 |
4.7 |
Ho |
1.3 |
1.4 |
1.1 |
1.3 |
1.4 |
1.1 |
1.3 |
1.1 |
1.0 |
0.8 |
1.0 |
1.0 |
1.2 |
1.1 |
1.2 |
Er |
2.4 |
2.6 |
2.2 |
2.5 |
2.7 |
2.2 |
2.3 |
2.0 |
2.0 |
1.6 |
2.0 |
2.0 |
2.3 |
2.2 |
2.2 |
Yb |
1.7 |
1.7 |
1.7 |
1.5 |
1.6 |
1.5 |
1.6 |
1.5 |
1.5 |
1.1 |
1.6 |
1.7 |
1.7 |
1.6 |
1.7 |
Lu |
0.3 |
0.3 |
0.4 |
0.3 |
0.3 |
0.3 |
0.3 |
0.3 |
0.3 |
0.2 |
0.4 |
0.3 |
0.4 |
0.3 |
0.4 |
Y |
30.5 |
39.1 |
28.2 |
31.9 |
34.5 |
27.6 |
34.1 |
25.7 |
25.0 |
18.3 |
23.2 |
25.2 |
25.7 |
27.0 |
28.0 |
Th |
9.8 |
15.5 |
8.8 |
22.2 |
17.6 |
8.9 |
7.0 |
11.8 |
8.8 |
7.2 |
7.6 |
7.4 |
8.8 |
7.2 |
7.1 |
Hf |
7.3 |
8.0 |
6.3 |
226.2 |
9.9 |
6.0 |
5.8 |
6.2 |
5.0 |
4.2 |
4.4 |
4.4 |
5.8 |
6.4 |
6.2 |
Note: DL-I, DL-II:
Đà Lạt (early and late phase), Plog: Phước Long, XL-I, XL-II: Xuân Lộc (early
and late phase), BMT-I, BMT-II: Buôn Ma Thuột (early and late phase), PL-I,
PL-II: Pleiku (early and late phase), PQ: Phú Quý, Re: Re Island, Qtri: Quảng
Trị, KPLg: Kông Plông, LPH: Lũng Pô Hồ (distribution seen in Fig. 1).
|
|
|
|
Figure 4. Features of composition of
incompatible elements in Cenozoic basalts
in Việt
Figure 5. Diagram of the relation between
incompatible elements and MgO
in Cenozoic basalts in Việt
XL - Xuân Lộc, Plog - Phước Long (other
symbols seen in Fig. 2)
Figure 6. Diagram of ratios between
incompatible elements in Cenozoic N-MORB
and E-MORB basalts in Việt
Note: 1) Đà Lạt; 2) Pleiku; 3) Buôn Ma
Thuột; 4) Xuân Lộc; 5) Phước Long; 6) Quảng Ngãi; 7) Quảng Trị; 8) Phú Quý;
9) Điện Biên Phủ; 10) Lũng Pô Hồ; 11) Khorat basalts (in Zhou et al, 1997);
SCB – East Sea basalts; NHRL – North hemisphere related line
Figure 7. Composition of isotopes of Cenozoic
basalts in Việt
basalts in Việt
MgO has common
correlation with P2O5, and basalts of the late phase have
quite richer P2O5 content than that of the early phase
(Fig. 3d). It is to note that basalts in Việt Nam have an extraordinary high H2O
content, up to 5% [7], that once more shows the great role of H2O in
particular, and liquid in general, in the forming process of basaltic magmas,
particularly in the late phase. Furthermore, the richness of liquid of
high-alkaline basalts is still expressed in the eruptive character and porous
structure of basalts of the late phase.
The clearly
positive correlation between MgO and CaO proves that the fractionated
crystallization is mainly of plagioclase and clinopyroxene that conforms to the
petrographic features of basalts [4, 11].
2. Composition of trace elements
On the diagram in
the Figure 4, the curve demonstrating components of incompatible elements
converted after primary mantle has the upward convex form, and similar to the
oceanic island basalt type reflects the enrichment of incompatible elements.
The major part of samples of Vietnamese basalts has Ta and Nb positive anomaly.
When the MgO content in the rocks increases (decrease of SiO2) the
content of incompatible elements also increases, furthermore basalts of the
late phase usually have higher content of high force field elements (HFSE) (for
example, mean Nb usually over 60 ppm), but basalts of the two phases are both
characterized by the low LILE/HFSE ratio (Fig. 6). The enrichment of light rare
earth elements and the high LREE/HREE ratio of basalts of the late phase can
reflect the difference or the inhomogeneity of the source. The Phước Long
basalts express the Ba deficit in comparing with Rb and Th (Fig. 6), in
contrast the Xuân Lộc and Đà Lạt basalts are rich in Rb, K and Ba in comparing
with other groups. While basalts of the major part of groups have the
overlapping of Rb/Sr (0.02 - 0.11) and Zr/Ba (0.2 - 0.6) ratios, basalts from
Phước Long have the Zr/Ba ratio of up to over 2.8 and those from Xuân Lộc and
Đà Lạt have the Rb/Sr ratio over 0.18 (Fig. 6).
IV. DISCUSSION
The stability of
MgO content in basalts of the early phase proves that they were a little
influenced by the process of fractionated crystallization. On the contrary,
basalts of the late phase have the strongly oscillating MgO content, proving a
higher degree of fractionated crystallization. The positive correlation between
MgO and CaO (Fig. 3) shows that the separation phase consists mainly of
plagioclase and clinopyroxene. However, the fractionated crystallization is
inconsiderable. According to former studies [4, 5, 12], the considerable
contamination of crustal materials has been observed in samples from isolated
effusive areas in the North, such as Phủ Quỳ, Điện Biên and Lũng Pô Hồ.
However, the effect of crustal contamination in basalts is, in general, not
great. One can say that the enrichment of incompatible elements in basalts
reflects the source peculiarity or level of partial melting more than the
effect of fractionated crystallization. On the Figure 6d the major part of
basalts falls into the E-
Experimental
studies have been showing that the composition of primary magmas depends on the
source composition, pressure, melting temperature and level of partial melting.
During the process of basaltic magma formation from peridotite mantle, the SiO2
content in the fluid depends on inverse proportion to pressure. When the
pressure decreases, the SiO2 content increases, and in contrast; at
the same time, together with the increase of decompression process the level of
partial melting also increases [3, 6, 7]. It is clear that the lower level of
partial melting in greater depths will lead to the enrichment of alkaline
components and incompatible elements, but to the SiO2 deficit (low
in SiO2). On the contrary, the great level of partial melting in
smaller depths should give the fluid having higher SiO2 content, but
lower content of alkali and incompatible elements. So, basalts of the early
phase (SiO2-high, MgO- and FeO-low) were formed in the conditions of
relatively low melting pressure (small depth), but of high level of partial
melting. On the contrary, basalts of the late phase (SiO2-low, MgO-
and FeO-high) have a higher melting pressure (greater depth) and more
restricted level of partial melting. According to former calculations the
basaltic magma of the early phase was formed in the depth of about 30-40 km, as
for the late phase the forming depth can reach up to 60-70 km [5, 9]. One can
say that the basaltic magma of the early phase was formed in the strong
extension condition with the uplift of the asthenospere; as for the late phase
it was formed in more limited extension condition. The features of major
element and trace element components of the two early and late phases reflect
rather clearly the above presented forming conditions of magmas.
According to [4,
5], after the isotopic components Cenozoic basalts in Việt
Although basalts
in Việt
Cenozoic basaltic
eruption in Việt
V. CONCLUSIONS
The Late Cenozoic
basalts is composed of two main groups corresponding to two eruptive phases:
early and late ones. Basalts of the early phase formed extensive basaltic
plateaux, including tholeiite and olivine tholeiite effusing along fractures,
while the late phase consists mainly of the effusion of central type with the
predominance of high-alkaline basalt and olivine tholeiite. Basalts of the
early phase are characterized by high SiO2 content and low content
of TiO2, FeO* and Na2O + K2O. On the contrary,
basalts of the late phase are characterized by low SiO2 content, but
high content of MgO, TiO2, FeO*, P2O5 and
specially high content of alkaline elements. In Cenozoic basalts of Việt
The authors
express their deep thanks to the
This work is
realized in the framework of the Project 710602 (2002-2004) with the support of
the Basic Research Program.
REFERENCES
1.
Flower M.F.J., Tamaki K., Hoang N., 1998. Mantle extrusion: A model for dispersed volcanism
and DUPAL-like asthenosphere in east Asia and western Pacific. In: M.F.J. Flower, S.L. Chung, C.H. Lo
(eds.), Mantle Dynamics and Plate Interactions in east Asia, Geodyn., 27:
67-88. AGU,
2. Gibson S.A.,
3.
4.
5.
6.
7. Latin D. and White N., 1990. Generating melt
during lithospheric extension: Pure shear vs. simple shear. Geology, 18: 327-331.
8.
9.
10.
11.
12.
13.
14. Rangin C.,
15.
16.
17. Wang J.H., An Yin,