Ar-Ar AGE OF MYLONITES AND GEODYNAMIC SIGNIFICANCE OF TRÀ BỒNG SHEAR ZONE, MIDDLE TRUNG BỘ

VŨ VĂN TÍCH1, NGUYỄN VĂN VƯỢNG1, HENRI MALUSKI2, CLAUDE LEPVRIER3

1University of Natural Sciences, Hà Nội National University, Nguyễn Trãi,  Hà Nội

2Montpellier II University, Montpellier, France; 3Paris 6 University, Paris, France

Abstract: The Trà Bồng shear zone is situated in Middle Trung Bộ and extends approximately 100 km from Khâm Đức Town to East Việt Nam Sea in E-W direction. Along this shear zone, all rocks are deformed into microgneiss, mylonite and ultramylonite. Tectonic criteria observed in the field show that this zone is affected by left-lateral shear. Two mylonitic samples of granodioritic and dioritic composition from this shear zone were dated by 40Ar - 39Ar method on their syn-kinematic biotite. The results indicated an Indosinian age between 223-243 Ma with more than 85% accumulated argon. The lower temperature steps indicated an Yanshan age between 70-100 Ma. The results of the study show that the Trà Bồng shear zone is a complex one and plays a role of an important boundary between Khâm Đức and Ngọc Linh Formations in Indosinian orogeny. The lower temperature steps may be related to magmatic activity in Yanshan orogeny.


INTRODUCTION

The Trà Bồng shear zone (TBSZ) is exposed on a length of 100 km, extending in east-west direction from the Khâm Đức Townlet through Trà Bồng and plunges under the Quaternary cover when reaching the East Việt Nam Sea. It is limited in its two sides by the Trà Bồng and Hưng Nhượng faults, and has the width of about 8 km in the widest section, gradually narrowing toward the Khâm Đức Townlet. At this locality the structural direction changes from E-W to NW-SE and joins the N-S trending Pô Cô shear zone.

Numerous shear zones accompanied by activities of deformation and metamorphism characterize the geologo-tectonic structure of the Vietnamese territory. They usually have the NW-SE trend that changes gradually to E-W, such as the Sông Mã, Sông Cả, Đại Lộc - Khe Sanh, etc. zones. The rocks of different primary lithological composition exposed along these zones are mylonitized, even ultramylonitized. Strike-slip activities accompanied by deformation-metamorphism took place in main relation to the Indosinian movement in about 245 Ma [3, 5] and renewed in younger stages [6]. On the structural pl.an the TBSZ has the parallel structural direction with the Đại Lộc - Khe Sanh shear zone. The set up problem is that the TBSZ has the same features of deformation-metamorphism and age as the above said shear zones or not? This paper presents the results of the study on petro-structural features, 40Ar-39Ar isotopic age and geodynamic significance of the TBSZ.

I. PETRO-STRUCTURAL FEATURES OF THE TRÀ BỒNG SHEAR ZONE

On the structural plan the TBSZ extends nearly 100 km from the Khâm Đức area, where it connects with the Pô Kô River fault zone, then extends in E-W direction to the Trà Bồng Townlet and plunges under Quaternary formations when reaching the East Sea (Fig. 1). This shear zone plays the role of the boundary between, on one side, sediments of the Ngọc Linh Group and on the other – the Khâm Đức Group; in some places it is covered by Mesozoic sediments of the Nông Sơn Basin. Exposed magmatic rocks are composed mainly of granite and granodiorite of the Chu Lai and Bến Giằng - Quế Sơn complexes. In the south there are mainly metamorphic rocks of the Ngọc Linh Group of the Kon Tum Block, including schists and gneisses, in some places migmatized and penetrated by Mesozoic granite.

 

Figure 1. Structuro-geological schema of the TBSZ
(simplification after geological maps at 1:200,000 scale)

Note: 1) Micaschist with C/S structure of the Khâm Đức Group; 2) Gneissic schist of the Ngọc Linh Group; 3) Schist of the Sa Thầy Formation; 4) Mylonite of the TBSZ; 5) Granite; 6) Deformed granite; 7) Granodioritic and dioritic orthogneiss; 8) Mafic and ultramafic rocks; 9) Quaternary sediments; 10) Faults; 11) S1 structural direction of laminated deformation; 12) Right shear, 13) Trà Bồng Fault; 14) Hưng Nhượng Fault; 15) Pô Kô Fault; 16) Sampling locality.

 

The TBSZ is formed by crystalline schist, amphibolite and intrusives of granodioritic - dioritic composition. It is bounded by two great faults: the Trà Bồng Fault in the north and the Hưng Nhượng one in the south. The width of the zone approximates 8 km that gradually decreases westward, when the zone changes the direction and joins the Pô Kô shear zone (Fig. 1). Almost all the rocks in the shear zone are very strongly deformed forming mylonites, even ultramylonites. Granite of the Hải Vân Complex penetrates the above deformed-metamorphic formations.

The study on the petro-structural characteristics has been carried out along sections perpendicular to the structural direction of the zone at Trà Bồng, Trà My and Khâm Đức. The results have been showing that almost all quartzite, micaschist, quartz schist, amphibolite and granite, granodiorite express very strong level of deformation and change into gneissic schist and mylonite. Mylonites have all the characteristic tectonic-L texture, almost impossible to distinguish the bedding or banded structure of primary rocks. The foliation feature is rather homogeneous along the zone, among that the structure of crystalline foliation is characterized by the alternation between mica-rich and quartz-feldspar-rich beds. The foliation direction changes in the interval of 90-110° and the foliation plane always dips southward with the dip changing from 70 to 80°, locally nearly vertical (Fig. 1b). The surface of these schists usually contains sillimanite, quartz and amphibole that are elongated forming the lineations and almost parallelly directed to the horizontal surface with the inclining angle of 0-10° (Fig. 1b). This structural feature shows that these schists were formed under the impact of the strike-slip process. The petro-dynamic indices (S/C, d, s) studied at different scale have been showing that the strike-slip activities correspond to the right shear direction (Fig. 1a, b).

The petrologic studies have been showing that mylonites have different petrographic composition, consisting mainly of quartzite, quartz-mica schist, dioritic orthogneiss, granodioritic orthogneiss and amphibolite. The analysis of paragenetic mineral associations of the pelitic rocks has been showing the major part of them is characterized by the association of quartz-muscovite-biotite- fibrous sillimanite ± andalusite. Under the microscope these minerals are all directed. As for the rocks of dioritic and granodioritic composition, they were formed by such minerals as: K-feldspar with inverse-perthitic texture, zonated yellow-brown hornblende, residual clinopyroxene and titanium-rich biotite. The presence of muscovite-biotite - fibrous sillimanite existing in equilibrium in metapelite and the existence of high-temperature minerals in metamorphic rocks of intrusive origin show that these mylonites were formed in high-temperature condition. Besides, the presence of andalusite proves the low mean pressure condition. The existence of these mineral associations shows that the studied rocks were metamorphosed and deformed in the conditions of rather high temperature and low mean pressure, and belong to the lower part of amphibolite facies.

So, the petro-structural study has been allowing to draw the following conclusions: the TBSZ passed through the metamorphic process characterizing the low mean pressure - rather high temperature conditions in the process of plastic deformation. The kinematic peculiarity of the shear zone is characterized by right strike-slip. For determining the age of this tectonic activity the authors have been taking the mylonite samples VN.284, VN.286 for age analysis by the 40Ar-39Ar method.

II. PETROGRAPHIC FEATURES OF ANALYZED SAMPLES

Aiming to date the activities of the TBSZ, the authors have been collecting samples, the formation of which was directly related to the moving process. Therefore, the two mylonite samples of diorite and granodiorite composition (VN.284 and VN.286) were directly collected in the TBSZ, among them the sample VN.284 was taken from the margin of the zone coinciding with the position of the Trà Bồng Fault. As for the sample VN.286, it is collected in the centre of the zone. These two different localities will allow to study on the evolution in space of the shear zone. The sampling localities are presented in the Figure 1a.

a) The mylonite sample VN.284 (15°15’08” N; 108°34’34” E) has granodioritic composition bearing quartz, K-feldspar, albite, andesine, hornblende, biotite, epidote, sphene and zircon. Almost all these rock-forming minerals are stretched and directed, proving the crystallization during the metamorphic process accompanying the ductile deformation.

b) The mylonite sample VN.286 (15°14’14”N; 108°37’59”E) has dioritic composition, characterizing the destruction in high temperature proved by the banding of quartz, albite, Ti-rich biotite, apatite, zircon and Fe oxides.

For analyzing the forming age of these mylonites, the syn-moving biotite from the above samples was taken for analyzing by the 40Ar-39Ar method.

III. RESULTS OF 40Ar-39Ar DATING

The syn-metamorphic-deformed biotite separated from mylonite samples was sent to Canada for the activation under the fast neutron flow; then it was analyzed by the gas mass-spectrometer Ar/Ar-Laser in the Laboratory of Geochronology of the Montpellier II University, France. The principle, technics and analytic condition have been applied after Maluski H. [4]. The results of analysis are presented in Table 1 and set forth in the form of diagram of plateau age and inverse isochrone diagram (36Ar/40Ar - 39Ar/40Ar) in Figure 2.

IV. DISCUSSION AND CONCLUSIONS

The advantage of the Ar-Ar isotopic dating method is that, it allows to recognize from low to high thermo-tectonic events in the same analyzed sample. Usually, Ar occurs from the radiation process from K existing in K-bearing minerals, keeping K in their lattice. When the minerals are impacted by a thermo-tectonic event, according to the degree of impact a part or all occurring argon is liberated from their lattice. If the mineral is impacted by a low temperature event, only a part of argon is lost in the position of low-energy levels (in the margin or in defects of the lattice structure). As for the argon stored in high-energy levels in the centre of the crystal lattice, it is lost only under the impact of metamorphic process at the temperature high enough for surpassing the threshold of its closing temperature. Therefore, with the technics of partial gas push the 40Ar-39Ar method allows to reflect different events that other methods cannot have.   

The results of 40Ar-39Ar age analysis have been showing that the biotite sample VN.286 gives the plateau age of 223 Ma (Fig. 2b). This value corresponds to 85% 39Ar liberated in high temperature. Besides, the age spectrum still gives a low-temperature value corresponding to over 10% of liberated 39Ar. The results calculated for these low-temperature levels are 100 Ma (Fig. 2b). The biotite sample VN.284 gives an older age. The calculated average age corresponding to 95% of liberated 39Ar is 243 Ma (Fig. 2a). Similar to the sample VN.286 the age spectrum of this sample gives also information on the low- temperature age clearly expressed through the corresponding plateau age in the first 3 levels. These first 3 levels corresponding to 5% liberated Ar give the average age value of 70 Ma (Fig. 2a). Due to the rather great errors of the levels, the authors have been checking the results by establishing the ischrone line on the inverse isochrone diagram for these first 3 levels. The obtained results give also the age values of about 68.7 ± 6 Ma (Fig. 2c), corresponding to the value of 36Ar/40Ar ratio of the primary atmospheric argon of 295.5 Ma. So, the two ways of demonstration have been giving the approximate values, proving that the samples have been recognizing a low-temperature phase.

 


Table 1. Results of age analysis by the block-spectrometer Ar-Ar Laser

Sample

40Ar*/39Ar

36Ar/40Ar

37Ar/39Ar

% 39Ar

% atmosphere

Age +/- 1sd

VN284 Biotite

x 1000. J =  0.0228

450

4.014

1.807

0.082

0.5

53.4

158 ± 30.6

500

2.476

1.838

0.078

1.0

54.3

99.0 ± 42.5

550

4.000

1.076

0.049

2.9

31.8

157.4 ± 9.4

600

5.490

0.390

0.015

7.9

11.5

212.7 ± 3.7

650

5.711

0.120

0.008

22.6

3.5

220.8 ± 1.5

700

5.864

0.056

0.005

46.4

1.6

226.3 ± .8

750

5.923

0.051

0.007

62.0

1.5

228.5± 1.2

800

5.949

0.055

0.023

66.2

1.6

229.5 ± 4.3

850

5.781

0.147

0.048

69.9

4.3

223.3 ± 5.2

900

5.511

0.100

0.061

75.3

2.9

213.5 ± 0.9

950

5.756

0.090

0.080

83.8

2.6

222.4 ± 2.3

1000

5.771

0.124

0.185

89.1

3.6

223.0 ± 3.3

1050

5.762

0.167

0.127

92.8

4.9

222.6 ± 5.1

1100

5.834

0.120

0.131

97.4

3.5

225.3 ± 3.7

1150

6.084

0.088

0.322

99.6

2.6

234.3 ± 7.8

1300

2.872

2.727

4.664

100

80.6

114.4 ± 51.5

VN286 Biotite

x1000. J = 0.0228

450

1.777

2.948

0.256

0.1

87.1

71.6±83.5

515

1.917

1.810

0.303

0.6

53.4

77.2±35.6

550

1.606

1.856

0.269

1.4

54.8

64.8±17.7

610

5.622

0.842

0.089

3.3

24.8

217.6±7.7

650

6.199

0.432

0.021

6.4

12.7

238.5±4.3

700

6.218

0.191

0.014

14.6

5.6

239.1±2.0

750

6.289

0.072

0.009

30.3

2.1

241.7±1.0

800

6.256

0.053

0.010

44.4

1.5

240.5±1.1

850

6.363

0.062

0.024

50.9

1.8

244.4±2.3

900

6.342

0.111

0.100

53.8

3.2

243.6±4.6

950

6.578

0.221

0.100

56.5

6.5

252.1±5.1

995

6.574

0.086

0.070

60.2

2.5

251.9±3.7

1050

6.223

0.161

0.046

62.3

4.7

239.3±6.4

1100

6.364

0.083

0.055

68.8

2.4

244.4±2.1

1150

6.305

0.068

0.026

80.6

2

242.3±1.3

1200

6.292

0.071

0.032

91.1

2.1

241.8±1.6

1250

6.254

0.116

0.047

98.6

3.4

240.5±1.9

1400

6.149

0.551

0.009

99.9

16.2

236.7±10.4

 



 

The results of 36Ar/40Ar age analysis on syn-metamorphic biotite of the above samples have been reflecting two age levels, recognizing two different phases of tectonic activities. The plateau age obtained in high-temperature level corresponding to 85 and 95% quantity of liberated Ar has been showing that the deformation-metamorphism activities of the TBSZ were concentrated in the interval of 223-243 Ma. Due to the closing temperature of biotite for the Ar isotope as 350° [1], this value corresponds to the deformation-metamorphism condition of the formation of mylonites. The forming age value of mylonite is similar to the Indosinian age obtained in the Sông and Đại Lộc - Khe Sanh shear zones in the region. This allows to affirm that granodiorite and diorite were formed at least before the Indosinian movement, then they were strongly deformed by the right strike-slip in 223-243 Ma forming these mylonites. Besides, the age spectrum of these samples has been allowing to recognize a younger thermo-tectonic event in the interval of 70-100 Ma. So, the TBSZ does not only recognize the deformation-metamorphism activities during the collision of Indosinian orogeny, but also the reactivation related to younger orogenic phase.

From the above said study results the following conclusions can be drawn: the TBSZ had a complicated history of tectonic activities. In this zone two different thermo-tectonic events can be recognized. The first event is the deformation activity accompanying metamorphism during the Indosinian orogeny in 223-243 Ma, then the second one is the Yanshan orogeny in 70-100 Ma. In the first event the TBSZ was a right strike-slip shear similar to other NW-SE trending shear zones in the Trường Sơn Range [2, 6, 7]. The degree of metamorphism accompanying the movement of the shear zone is rather high, corresponding to the amphibolite facies. This proves that the deformation-metamorphism activities of the zone were related to larger movements of the Earth’s crust in the region. The presence of a deformation zone of large scale shows that the TBSZ played an important boundary role between the Khâm Đức and Ngọc Linh Groups. Similar to large deformation zones in the Trường Sơn Range, the TBSZ is an important branch of the structuro-tectonic plan in the period of Indosinian tectonic activities. In the phase of 70-100 Ma, mylonites have been recognizing a low-temperature tectonic event, that, possibly, was related to the thermal increase of intrusive magmatism happening during the Yanshan orogeny.

Acknowledgement: This paper is realized in the framework of the Project No. 713204 with the support of the Basic Research Program. The authors would like to express their deep thanks.

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