FEATURES OF ARSENIC DISTRIBUTION IN GROUNDWATER OF
ĐỖ
VĂN B̀NH
Hà Nội
Abstract: A
research on arsenic distribution in groundwater with the aim to minimise its
negative effects on public health is very necessary.
I. GEOGRAPHIC
LOCATION
Nam Định is a province
lying on the Red River Delta. In the northwest, it is bounded by Hà
Land in
Climate in
II. HYDROGRAPHIC
FEATURES
The stream
network in this area is rather dense. The more it extends to the sea, the more
it is denser. Among the rivers, there are Red, Đáy, Đào, and Ninh
Cơ ones. In the rainy season, the water level in rivers is high, and the
water flow is strong. On the contrary, in the dry season, the water level in
rivers is low, the water flow is gentle. Besides, the water level in rivers depends
on tide.
The unique
features of river in this area are that, the flow is bendy and winding clearly.
It proves that the speed of flow is slow and the slope of river-bed is gentle
and the rivers are rather long. The mentioned above rivers pour a huge water
amount into the sea every year. The average water output of the
In
(Calcium-magnesium bicarbonate)
In
Tân Đệ ferry-boat:
(Sodium-calcium-magnesium
chloride)
According to monitored data, tidal regulations in
Table 1. Specific characteristics of tidal water
level in the Văn Lư Monitoring Station
Months |
1 |
2 |
3 |
4 |
5 |
6 |
7 |
8 |
9 |
10 |
11 |
12 |
h |
156 |
155 |
159 |
154 |
158 |
158 |
160 |
162 |
173 |
191 |
184 |
167 |
hmax |
275 |
276 |
253 |
271 |
281 |
282 |
286 |
301 |
306 |
306 |
311 |
311 |
hmin |
-11 |
11 |
13 |
42 |
26 |
2 |
4 |
-9 |
1 |
29 |
14 |
-2 |
h: Water level of
tide/month (cm), hmax: Highest water
level of tide (cm)
hmin: Lowest water level
of tide (cm), (-): Water level of tide
under zero (cm).
III. POPULATION -
ECONOMY
Population in the area mainly belongs to Kinh people. Population density is
about 800-1000 people/km2. Rice culture is the main way of living in
Traffic
here is very easy. Roads are dense with a network of interprovincial roads,
interdistrict roads and intercommunal roads, etc.. Interprovincial roads
consist of Highways 10, 21, 55 linking
IV. GEOLOGICAL AND
HYDRO-GEOLOGICAL CHARACTERISTICS
In
-
Marine-lacustrine porous mixed sediment aquifer of Holocene age (qh);
- Marine
aquitard sediments of Pleistocene age of Vĩnh Phúc Formation (qp3);
- Porous
sediment aquifer of Pleistocene age of Hà Nội Middle-Upper Subformations
(qp2-3);
- Porous,
porous-bedding sediment aquifer of Miocene - Early Pleistocene age (qp-m2);
The main
characteristics of each hydrogeological unit distributed in the study area are
described as follows (in descending order):
1.
Marine-lacustrine porous mixed sediment aquifer of Holocene age of Thái B́nh
Formation (qh)
The Holocene aquifer consists of water-bearing beds of
the Thái B́nh and Hải Hưng formations. The Thái B́nh Formation is
distributed largely in the Hải Hậu, Nghĩa Hưng, Giao Thủy,
Xuân Trường and Nam Trực districts, Nam Định
Province. It is composed mainly of loams and sand lenses, in some
places with clay layers and multioriginal loam. Groundwater usually exists in
these sand lenses and loam. The thickness of sand lenses is often from 8 to 10
m, in some places up to 12-15 m. Results
obtained from tests in some drill holes show that: water level h = 1-3 m, flow rate q = 0.01-0.5 l/ms, hydraulic
conductivity K = 0.2-1.3 m/day.
The chemical composition and total mineralization
(TDS) change irregularly, depending on soil features, formation features of
water-bearing sand lenses. The water basically is in the form of sodium
chloride.
Main
source supplying water for this aquifer is rain water and surface water. In
some districts, such as Xuân Trường,
Giao Thủy, Hải Hậu and Nghĩa Hưng, there exists
fresh-water lens of small thickness in coastal dunes. The source of fresh-water
in these lenses is rainy water. However, in many places, such as Xuân Trường
and Giao Thủy, this aquifer is invaded by sea-water during the tide rise
and the whole area of this aquifer is semi-salted and as the result, the water
is not usable.
The Hải
Hưng Formation is distributed largely in the areas and is covered by
younger sediments of the Thái B́nh Formation. Sediments of different origins
comprise blue-grey clay, silty sand, … The water-bearing sand layer has relatively
stable depth, usually ranging from 12-15 to 22-25 m.
The total
water mineralization of this formation changes irregularly and it exists
fresh-water lens (TDS M <1 g/l). Chemical composition of water is
bicarbonate, bicarbonate-chloride changing gradually into chloride-bicarbonate.
In
general, the water quantity in this formation is not great and the quality is
not good, so the water here is only used for supplying to households in the
river side.
2. Marine aquitard
sediments of Pleistocene age of Vĩnh Phúc Formation (qp3)
Sediments
of the Vĩnh Phúc Formation are largely distributed in the area and are
covered by the Hải Hưng and Thái B́nh Formations. They are mainly
composed of clay, silty clay mixed with lateritic gravel. Their thickness
changes from 20 to 25 m. The study results show that average hydraulic conductivity K = 0.05 m/day, maximum Kmax = 0.07
m/day.
3. Porous sediment
aquifer of Pleistocene age of Hà Nội Middle-Upper Subformations (qp2-3)
Sediments
of Pleistocene age of the Hà Nội Formation are largely distributed in the
Red River Delta and are seperated from aquifer of Hải Hưng Formation
by the water registering clay layer of the Vĩnh Phúc Formation. They are
mainly composed of quartz gravel, cobble, and in some places, stones and gravel
mixed with silty sand and silty clay.
Based on
drilling data, it can be seen that the depth of aquifers is relatively stable
and regular.
If looking
at the S-N cross section, or from the sea to the mainland, in the north of the
study area (south of Vụ Bản District), the aquifer lies in the
shadowest direction, 30-35 m in the depth. In the centre of Hải Hậu
District, the aquifer lies in the depth of 80-90 m, in some places up to
hundreds metres or more. Toward the seaside, the aquifer lies in the depth of 60-70
m. The depth of aquifer changes regularly. In the northwest of the area (south
of Ư Yên and Vụ Bản Districts), the depth of aquifer is smallest
(5-10 m). The more the aquifer stretches to the sea, the thicker it is. In some
places, its thickness is 30-50 m. Its average thickness is 28.4 m.
Results obtained from the borehole 109 show that: in
Trực Phú commune, Trực Ninh District, the water level h = 0.25 - 2.5 m, flow rate unit q = 1.5 - 8.89
l/ms, coefficient of transmissibility T = 500 - 1000 m2/day.
Results from analyzed water samples in the wells show
that the total mineralization changes from 0.3 to 3 g/l. The chemical
composition of water is sodium-magnesium bicarbonate or sodium chloride.
In the study areas, a fresh-water lens with large distribution
has been found. It belongs to the Hải Hậu, Nghĩa Hưng, Trực
Ninh and south part of Nam Trực districts. It will be discussed more in
details in the following part.
There are not data that show the hydraulic relationship
between surface water (Red River, Đáy River and Ninh Cơ River) with
groundwater of the Hà Nội Formation.
4. Porous,
porous-bedding sediment aquifer of Miocene - Early Pleistocene age (m2-qp)
This aquifer is composed of sediments of Thái Thụy
Formation and Neogene sediments. They are distributed in the lowest part of
hydrogeological cross section in the study area. This aquifer is not exposed on
the surface, but is covered by Quaternary sediments. It is distributed in the
northeast of the faults F4, F6. In the southwest, it
comes into contact with the Đồng Giao Formation (T2a
đg) through the Fault F6,
in the west, with the Sông Hồng Group (PP sh) through the Faults F8 - F3 - F4.
These
sediments are mainly composed of sand, gravel interbedded with sandstone. The
pressure of this aquifer is strong. The analytic results show that: capacity Q = 1-12 l/s, flow rate unit q = 2-6
l/s, pressure coefficient of transmissibility T = 16-438 m2/day. The chemical composition of water changes
irregularly depending on the depth. In the depth of 250 m in Nghĩa
Hưng District, the water is fresh, but with the same depth in other
districts, it is salted.
V. STATE OF
The total quantity of water consumed in
1. Large
exploitation: This form of water exploitation consists of
exploited groundwater in wells with huge capacity in different places. Capacity
is from hundreds to thousands of m3/day. In
2. Small
exploitation: This form consists of exploiting from drilled and
digged wells in households. It is very popular in rural areas of the country.
In
In
districts and communes of Nam Định Province, there are only two
towns (Cổ Lễ and Ngô Đồng) and three district centres
(Nam Trực, Mỹ Thịnh, and Xuân Trường) setting up a
network of water supply. However, there are few households using this water
supply system.
Besides,
in communes there are other water supply forms as follows:
- A
network of water supply in commutation: capacity of 600-1,800 m3/day.
The water is groundwater or surface water and then it is treated by filtering
and decontaminating, and then pumping to houses.
- A
network of water supply from drilled wells. This network helps to upgrade the
effectiveness of UNICEF drilled wells and to limit the number of drilled wells
unused and to restrict groundwater pollution. Centre of living water and rural
environment has set up a network of water supply in places, such as Đoài
Village, Yên Bảng Commune; Hải Thịnh commune, Hải Hậu
District; hospital in Mỹ Lộc District.
This network of water supply was set up since 1984. According to
surveyed data up to now there are 76,238 drilled wells with the depth of from
15-25 to 90-130 m in the whole province. State of supplying water in the
country is shown in Table 2.
Table 2. Number of drilled wells in Nam Định
Province
Districts |
Nghĩa Hưng |
Hải Hậu |
Giao Thuỷ |
Xuân Trường |
|
Trực Ninh |
Wells number |
23,542 |
26,267 |
2,931 |
4,031 |
2,156 |
7,673 |
VI. STATE OF
In order
to evaluate the state of arsenic pollution of groundwater in
A total of
17,320 samples are taken and analyzed, among them, 25% are analyzed by the
standard modern method and the rest – by test KID method, which is not as exact
as in-house analysis, but popular in survey in and outside the country. Samples
analyzed exceeding the value of 0.05 mg/l are presented in Table 3.
The
results from analyzing As in
Table 3.
Number of groundwater samples with content of over 0.05 mg/l in districts
No. |
Districts |
Groundwater samples
>=0.05mg/l |
1 |
Giao Thủy |
61 |
2 |
Mỹ
Lộc |
291 |
3 |
|
93 |
4 |
|
214 |
5 |
Nghĩa
Hưng |
3 |
6 |
Trực
Ninh |
111 |
7 |
Vụ
Bản |
78 |
8 |
Xuân Trường |
82 |
9 |
Ư Yên |
40 |
10 |
Hải Hậu |
10 |
11 |
Total |
983 |
The map of
As distribution in
Figure 1. Diagram of As location in groundwater in
Figure 2. Scheme of locations of As samples from
groundwater in
The orange
colour (As: 0.025-0.05 mg/l) appears in a map in a spotted form and appears in
all surveyed districts.
The yellow
colour (As: 0.01-0.025 mg/l) appears largely in the map and largest stretching
from Trực Ninh to Nghĩa Hưng. Besides, it appears in spotted
form in many places.
The blue
colour (As <0,01 mg/l) shows places are safe for As. This colour appears in
the spotted alternate form, but occurs largely in south Hải Hậu
(Fig. 2).
It can say
that groundwater in
Table 4. As
content in grounwater in
Samples No. |
Samples under 0.01 mg/l |
Samples from 0.01 to 0.025 mg/l |
Samples from 0.025 to 0.05 mg/l |
Samples from 0.05 mg/l above |
17,320 |
11,249 |
4,802 |
286 |
983 |
The study on As origin shows that As lies
in clay-mud sediments containing organic matter. When the water chemistry
changes, As moves from sediments into water under a complex mechanism.
VII. CONCLUSIONS
1. Among aquifers in Nam Định Province, the
Pleistocene Aquifer plays an important role in water supply, but it is polluted
by As. When exploiting for use, it is necessary to treat water.
2. Porous aquifer, porous-bedding sediments
of Late Miocene - Early Pleistocene age (m2-qp1) has not been carefully studied so they
have not been having an evaluation on As pollution.
3. Origin and
movement of As in groundwater in Nam Định have not been carefully
studied, so they need to be continued to be studied in the coming time, aiming
to supply with safe water to local people.
REFERENCES
1. Bùi Học (Editor),
2005. Evaluating the stability of exploiting and using groundwater in Việt
Nam. Strategic orientation of exploiting and protecting groundwater resource
until 2020. Hà Nội University of
Mining and Geology (in Vietnamese).
2.
Dept of Water Management, 2008. Report on surveyed results
of As pollution reality in natural groundwater and water in wells in households
– Part 1. Hà Nội.
3.
Đỗ Văn B́nh, 2006. Formation and
distribution of As in groundwater in Quaternary in Hà Nội. Evaluation,
forecast and sollution to minimize bad effects of As on water for living. Ph.D thesis, Hà Nội Univ. of Mining
and Geology (in Vietnamese).
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(in Vietnamese).
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